Notice bibliographique
- Notice
Type(s) de contenu et mode(s) de consultation : Texte noté : électronique
Titre(s) : Olefin metathesis [Texte électronique] : theory and practice / edited by Dr. Karol Grela, Institute of Organic Chemistry, Kasprzaka, Poland
Publication : Hoboken, New Jersey : Wiley, [2014]
Description matérielle : 1 online resource
Note(s) : "Zespol III.". - Includes bibliographical references and index. - Description based on print version record and CIP data provided by publisher.
This is a complete examination of the theory and methods of modern olefin metathesis,
one of the most widely used chemical reactions in research and industry. Provides
basic information for non-specialists, while also explaining the latest trends and
advancements in the field to experts. Discusses the various types of metathesis reactions,
including CM, RCM, enyne metathesis, ROMP, and tandem processes, as well as their
common applications. Outlines the tools of the trade-from the important classes of
active metal complexes to optimal reaction conditions
Autre(s) auteur(s) : Grela, Karol (1970-....). Fonction indéterminée
Sujet(s) : Métathèse (chimie)
Catalyse
Alcènes
Livres numériques
Indice(s) Dewey :
547.215 (23e éd.) = Catalyse (chimie organique)
Identifiants, prix et caractéristiques : ISBN 9781118711613
Identifiant de la notice : ark:/12148/cb446548635
Notice n° :
FRBNF44654863
(notice reprise d'un réservoir extérieur)
Table des matières : Title Page; Copyright; Preface; Reference; Contributors; Part I: Applications of Olefin
Metathesis Reactions; Section 1: Introduction; Chapter 1: Olefin Metathesis Reactions:
From A Historical Account to Recent Trends; 1.1 Introduction; 1.2 The Metathesis Reactions:
Exchanges of Carbenes and Carbynes; 1.3 The Early Days of Olefin Metathesis in American
Industry; 1.4 Unsuccessful Attempts to Solve the Mechanistic Puzzle; 1.5 The Chauvin
Mechanism: A Metathesis Dance; 1.6 The Importance of the Chauvin Mechanism for Overall
Organometallic Catalysis
1.7 Schrock's High Oxidation State Alkylidene and Alkylidyne Complexes1.8 Grubbs'
Approach and the Ru Olefin Metathesis Catalysts; 1.9 Olefin Metathesis in Aqueous
Solvents and Water; 1.10 Olefin Metathesis in Other "Green Solvents": Ionic Liquids
and CO2; 1.11 Solid Catalyst Supports; 1.12 Metal Contamination of the Metathesis
Reaction Products; 1.13 Industrial Applications; 1.14 Applications to Organic Synthesis;
1.15 Alkyne Metathesis; 1.16 Alkane Metathesis; 1.17 Polymerization Metathesis and
Polymer Materials; 1.18 Concluding Remarks; Acknowledgments; References
Section 2: Types of Olefin Metathesis ReactionsChapter 2: Cross Metathesis; 2.1 Introduction;
2.2 Functional Group Influence on the Metathesis Outcome; 2.3 E/Z Selectivity Control;
2.4 Outlook and Perspectives; Acknowledgments; References; Chapter 3: Ring-Closing
Metathesis; 3.1 Introduction; 3.2 General Factors in Cyclization Efficiency; 3.3 Scope,
Challenges, and Opportunities; 3.4 Practical Aspects; 3.5 Practical Examples; 3.6
Industrial Applications of RCM; 3.7 Conclusions; Acknowledgments; References; Chapter
4: Ene-Yne Metathesis; 4.1 Introduction
4.2 Ene-Yne Metathesis not Involving Cascades4.3 Tandem Processes Involving En(e)Yne
Metathesis; 4.4 Conclusion and Outlook; References; Chapter 5: Domino and other Olefin
Metathesis Reaction Sequences; 5.1 Introduction; 5.2 Domino Reactions; 5.3 Metathesis/Non-Metathesis
Reaction Sequences; References; Chapter 6: Enantioselective Olefin Metathesis; 6.1
General Introduction; 6.2 Asymmetric Ring-Closing Metathesis (ARCM); 6.3 Tandem Asymmetric
Ring-Opening/Cross Metathesis (AROM/CM) or Tandem Asymmetric Ring-Opening/Cross-Closing
Metathesis (AROM/RCM); 6.4 Conclusion; References
Chapter 7: Olefin Metathesis Polymerization7.1 Introduction; 7.2 ROMP-The Mechanism;
7.3 The Initiators/Catalysts; 7.4 ROMP-The Monomers; 7.5 ROMP-Applications; 7.6 Acyclic
Diene Metathesis; 7.7 Cyclopolymerizations; 7.8 Conclusions; References; Section 3:
Applications of Olefin Metathesis Reactions; Chapter 8: Applications in the Synthesis
of Natural and Biologically Active Molecules; 8.1 Introduction; 8.2 Ring-Closing Metathesis
(RCM); 8.3 Relay Ring-Closing Metathesis (RRCM); 8.4 Temporary Tether and RCM (TT-RCM);
8.5 Cross-Metathesis (CM); 8.6 Ring-Opening Metathesis (ROM)