Notice bibliographique
- Notice
Type(s) de contenu et mode(s) de consultation : Texte noté : électronique
Titre(s) : Clathrochelates [Texte électronique] : synthesis, structure, and properties / edited by Yan Z. Voloshin, Nina A. Kostromina, Roland Krämer
Édition : 1st ed.
Publication : Amsterdam ; Boston : Elsevier Science, 2002
Description matérielle : 1 ressource dématérialisée
Note(s) : Includes bibliographical references (pages 401-416) and index
Clathrochelates are compounds which contain a metal ion encapsulated within a three
dimensional cage of macrobicyclic ligand atoms. Within this cage the metal has unique
properties and is to a great extent isolated from environmental factors. Such complexes
are suitable as models of the most essential biological systems, membrane transport,
electron carriers, highly selective and sensitive analytical reagents, catalysts for
photochemical and redox processes, cation and anion receptors, etc. The aim of this
monograph is to generalize and analyze experimental and theoretical data on clathrochelates
in order to promote further research in this promising field of chemistry. Chapter
1 gives general concepts of complexes with encapsulated metal ions, discusses basic
specific features of these compounds, considers and characterizes the main types of
compounds with encapsulated metal ions and the main classes of clathrochelates, and
includes the current nomenclature. Chapter 2 deals with the pathways of clathrochelate
synthesis and the general procedures for the synthesis of macrobicyclic tris-dioximates,
phosphorus-containing tris-diiminates, sepulchrates, sarcophagi-nates, and polyene
and other types of clathrochelate complexes. Chapter 3 concerns studies of the electronic
and spatial structure of clathrochelate complexes. In Chapter 4, the kinetics and
mechanism of synthesis and decomposition reactions of macrobicyclic tris-dioximates,
sarcophaginates, and sepulchrates in solution and gas phases are discussed. Chapter
5 considers the electrochemical, photochemical, and some other characteristics of
clathrochelates and their applications associated with these characteristics. Finally,
the practical applications of the unique properties of clathrochelates and perspectives
on the synthesis of new clathrochelates are described in Chapters 6 and 7, respectively
Autre(s) auteur(s) : Voloshin, Yan Z.. Fonction indéterminée
Kostromina, Nina Anatolʹevna. Fonction indéterminée
Krämer, Roland. Fonction indéterminée
Sujet(s) : Clathrochélates
Indice(s) Dewey :
547.590 44242 (23e éd.) = ; 547.59 (23e éd.) = Composés hétérocycliques
Identifiants, prix et caractéristiques : ISBN 9780444512239
Identifiant de la notice : ark:/12148/cb44646415g
Notice n° :
FRBNF44646415
(notice reprise d'un réservoir extérieur)
Table des matières : Ch. 1 ; Fundamental concepts of complexes with encapsulated metal ions --Ch. 2 ; Synthesis
of clathrochelates --Ch. 3 ; Spatial and electronic structure of clathrochelates --Ch.
4 ; Kinetics and mechanism of synthesis and decomposition of clathrochelates --Ch.
5 ; Properties of clathrochelates --Ch. 6 ; Application possibilities of clathrochelate
chemistry --Ch. 7 ; New types of clathrochelates: perspectives of synthesis.