Notice bibliographique
- Notice
Type(s) de contenu et mode(s) de consultation : Texte noté : électronique
Titre(s) : Kinetic control in synthesis and self-assembly [Texte électronique] / editors, Munenori Numata, Shiki Yagai, Toshiyuki Hamura
Publication : London : Elsevier Ltd. : Academic press, copyright 2018
Description matérielle : 1 online resource
Note(s) : Notes bibliogr. Index
Kinetic Control in Synthesis and Self-Assembly provides a unique overview of the fundamental
principles, novel methods and practical applications for researchers across organic
synthesis, supramolecular chemistry and materials sciences. The book examines naturally
occurring molecular systems in which kinetic processes are more ubiquitous than thermodynamic
processes, also exploring the control of reactions and molecular self-assemblies,
through kinetic processes, in artificial systems. These methods currently play a crucial
role for tuning materials functions. From organic synthesis, to supramolecular assemblies,
and from restricted spaces, to material synthesis for hierarchical structures, the
book offers valuable coverage for researchers across disciplines. Interesting topics
include how to regulate kinetic pathways more precisely, essential molecular design
for kinetic traps, and how molecular environments surrounding molecules (i.e., solvent,
temperature, and pressure effects) influence kinetic control in reactions and self-assemblies
Autre(s) auteur(s) : Numata, Munenori. Éditeur scientifique
Yagai, Shiki. Éditeur scientifique
Hamura, Toshiyuki. Éditeur scientifique
Sujet(s) : Synthèse organique
Autoassemblage
Chimie supramoléculaire
Cinétique chimique
Indice(s) Dewey :
547.2 (23e éd.) = Réactions chimiques organiques
Identifiants, prix et caractéristiques : ISBN 9780128121276. - ISBN 0128121270. - ISBN 9780128121269 (erroné). - ISBN 0128121262
(erroné)
Identifiant de la notice : ark:/12148/cb45736608v
Notice n° :
FRBNF45736608
(notice reprise d'un réservoir extérieur)
Table des matières : 3.2 Kinetic Products and Thermodynamic Products in Ring Closure Reaction of S-DR33.3
Kinetic Stabilization by Bulky Aryl Group; 4. KINETIC STABILIZATION BY S̀̀TRETCH EFFECT'';
4.1 Type 1: Spirobonding; 4.2 Type 2: Macrocyclic System; 5. SUMMARY; REFERENCES;
2 ; Dynamic Kinetic Resolution for Asymmetric Synthesis: Synergy of Hydrolase and
Metal Catalysts; 1. INTRODUCTION; 2. GENERAL ASPECTS OF HYDROLASE-CATALYZED KINETIC
RESOLUTION AND DYNAMIC KINETIC RESOLUTIONS; 3. HYDROLASE/METAL COMBO-CATALYZED DYNAMIC
KINETIC RESOLUTION; 4. SYNTHETIC APPLICATIONS OF DYNAMIC KINETIC RESOLUTION; 5. SUMMARY
3.2 Divergent Synthesis of Polyacene Derivatives4. CONCLUSION; REFERENCES; 4 ; Control
of Inversion Kinetics of Bowl-Shaped Aromatic Compounds; 1. INTRODUCTION; 2. PRISTINE
BUCKYBOWLS; 3. SUBSTITUTED BUCKYBOWLS; 4. HETEROBUCKYBOWLS; 5. SUMMARY; REFERENCES;
5 ; Asymmetric Hydrogenation of Aromatic Carbocycles; 1. INTRODUCTION; 2. ASYMMETRIC
HYDROGENATION OF AROMATIC CARBOCYCLES WITH CHIRAL AUXILIARY; 3. CATALYTIC ASYMMETRIC
HYDROGENATION OF AROMATIC CARBOCYCLES; 4. SUMMARY; REFERENCES; 6 ; Kinetic Control
in Natural Product Synthesis; 1. INTRODUCTION; 2. PALAU'AMINE
3. SYNTHESIS OF CYCLIZATION PRECURSOR 44. SINGLE-STEP CONSTRUCTION OF ABDE TETRACYCLIC
RING CORE USING KINETIC CONTROL CONDITION; 5. TOTAL SYNTHESIS OF PALAU'AMINE; 6. CONCLUSION;
REFERENCES; 7 ; Influence of Glycosylation Pattern on Protein Biodistribution and
Kinetics In Vivo Within Mice; 1. INTRODUCTION; 2. SYNTHETIC METHODS OF N-GLYCOSYLATED
PROTEINS; 2.1 Lysine Residue Conjugation; 2.2 Cysteine Residue Conjugation; 2.3 Bioorthogonal
Reaction-Based Conjugation; 2.4 Enzymatic Glycosylation; 3. IMAGING METHODS FOR N-GLYCOSYLATED
PROTEIN BIODISTRIBUTION